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Saint Urbain: Teaches basic and advanced miracles.Freke's Apprentice: Teaches basic spells in exchange for souls.He cannot teach all of the spells that Yuria can teach. He must be freed from a cell on the third floor of the eastern Prison of Hope before he appears in the Nexus. Sage Freke: Teaches basic and advanced spells.She must be found in a tower beyond the Tower Knight Archstone before she appears in the Nexus. Yuria the Witch: Teaches advanced spells in exchange for Demon's Souls.Patches appears in front of the Archstone of the Tower Queen after the player has spoken with him on the cliffs beneath the Armor Spider Archstone and behind the altar just beyond the Adjudicator Archstone. Patches the Hyena: Sells various items, a few rings, and higher-level ammunition.Boldwin, unlike Ed, only handles standard or Quality upgrades. Blacksmith Boldwin: Sells weaponry, ammunition and does basic repairs and upgrades for your weapons.The only penalty for answering "no" is being unable to acquire the Friend's Ring from the Monumental, even after gaining Pure White Character Tendency the Monumental will still unseal the Archstones whatever the player's answer is.
Its worth noting that you keep everything that he has through to NG+, when you make it there. Stockpile Thomas: Stores all your items through the game.